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Engineered Porous Electrodes to Unlock Ultra-low Cost Fe-Air Redox Flow Batteries

Objective

This proposal will develop a game-changing paradigm to design, synthesize, and functionalize porous electrode materials with far-reaching consequences in electrochemical science and engineering. Focusing on the Fe-air redox flow battery (FAIR-RFB), which holds promise for low-cost, long duration energy storage, I will employ an interdisciplinary approach bridging (electro)chemical engineering, materials science, and computational design to address the following fundamental challenges:

(1) I will elucidate the role of the porous electrode microstructure. I will introduce a new methodology that couples evolutionary algorithms with microstructure-informed simulations to predict ideal electrode geometries. A versatile synthetic platform, non-solvent induced phase separation, will be leveraged to synthesize highly controlled 3D microstructures and train neural networks to accelerate the discovery of optimal geometries.

(2) I will determine to what extent surface moieties of the porous electrode influence transport phenomena, kinetics, and durability. I will employ electrografting of select molecules to functionalize porous electrodes and impart functional properties (wettability, activity, stability). I will perform nanoelectrochemical imaging to elucidate the role of electrode-coating-electrolyte phenomena.

(3) I will develop a novel electrochemical reactor architecture for high-power Fe-air RFBs. Building upon the two previous developments, I will synthesize tailored iron and air electrodes and leverage polymeric bipolar membranes to realize a high voltage and low resistance electrochemical cell. Advanced imaging techniques, i.e. energy- and wavelength-selective neutron imaging, will be employed to visualize reactive transport phenomena during operation, thus helping to address these questions.

The novel approaches developed in FAIR-RFB will enable breakthroughs in performance and durability of large-scale electrochemical energy storage systems.

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Keywords

Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)

Programme(s)

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Topic(s)

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Funding Scheme

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HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) ERC-2021-STG

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Host institution

TECHNISCHE UNIVERSITEIT EINDHOVEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 999 958,00
Address
GROENE LOPER 3
5612 AE Eindhoven
Netherlands

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Region
Zuid-Nederland Noord-Brabant Zuidoost-Noord-Brabant
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 999 958,00

Beneficiaries (1)

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